Almandine

Almandine
General
CategoryNesosilicate
Formula
(repeating unit)
Fe2+
3
Al
2
Si
3
O
12
IMA symbolAlm[1]
Strunz classification9.AD.25
Crystal systemCubic
Crystal classHexoctahedral (m3m)
H–M symbol: (4/m 3 2/m)
Space groupIa3d
Identification
Colorreddish orange to red, slightly purplish red to reddish purple and usually dark in tone
Cleavagenone
Fractureconchoidal[2]
Mohs scale hardness7.0–7.5
Lustergreasy to vitreous
Streakwhite
Specific gravity4.05+0.25
−0.12
[2]
Polish lustervitreous to subadamantine[2]
Optical propertiesSingle refractive, and often anomalous double refractive[2]
Refractive index1.790±0.030[2]
Birefringencenone
Pleochroismnone
Dispersion0.024[2]
Ultraviolet fluorescenceinert
Absorption spectrausually at 504, 520, and 573 nm, may also have faint lines at 423, 460, 610 and 680–690 nm[2]
References[3][4][5]

Almandine (/ˈælməndɪn/), also known as almandite, is a species of mineral belonging to the garnet group. The name is a corruption of alabandicus, which is the name applied by Pliny the Elder to a stone found or worked at Alabanda, a town in Caria in Asia Minor. Almandine is an iron alumina garnet, of deep red color, inclining to purple. It is frequently cut with a convex face, or en cabochon, and is then known as carbuncle. Viewed through the spectroscope in a strong light, it generally shows three characteristic absorption bands.[6]

Almandine is one end-member of a mineral solid solution series, with the other end member being the garnet pyrope. The almandine crystal formula is: Fe3Al2(SiO4)3. Magnesium substitutes for the iron with increasingly pyrope-rich composition.

Almandine, Fe2+
3
Al
2
Si
3
O
12
, is the ferrous iron end member of the class of garnet minerals representing an important group of rock-forming silicates, which are the main constituents of the Earth's crust, upper mantle and transition zone. Almandine crystallizes in the cubic space group Ia3d, with unit-cell parameter a ≈ 11.512 Å at 100 K.[7]

Almandine is antiferromagnetic with the Néel temperature of 7.5 K. It contains two equivalent magnetic sublattices.[8]

  1. ^ Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi:10.1180/mgm.2021.43. S2CID 235729616.
  2. ^ a b c d e f g Gemological Institute of America, GIA Gem Reference Guide 1995, ISBN 0-87311-019-6
  3. ^ Mindat.org - Almandine
  4. ^ Webmineral.com - Almandine
  5. ^ "Handbook of Mineralogy - Almandine" (PDF). Archived from the original (PDF) on 2016-03-03. Retrieved 2013-03-01.
  6. ^ One or more of the preceding sentences incorporates text from a publication now in the public domainChisholm, Hugh, ed. (1911). "Almandine". Encyclopædia Britannica. Vol. 1 (11th ed.). Cambridge University Press. p. 712.
  7. ^ Geiger, C.; Armbruster, Th.; Lager, G.; Jiang, K.; Lottermoser, W.; Amthauer, G. (1992). "A combined temperature dependent 57Fe Mössbauer and single crystal X-ray diffraction study of synthetic almandine: evidence for the Gol'danskii–Karyagin effect". Physics and Chemistry of Minerals. 19 (2): 121–126. Bibcode:1992PCM....19..121G. doi:10.1007/BF00198609. S2CID 98610041.
  8. ^ Zherebetskyy, Danylo (2010). Quantum mechanical first principles calculations of the electronic and magnetic structure of Fe-bearing rock-forming silicates (PhD). Dissertation.com, Boca Raton, Florida. ISBN 978-1-59942-316-6.

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