Amylopectin

Amylopectin
Identifiers
ChemSpider
  • None
ECHA InfoCard 100.029.907 Edit this at Wikidata
EC Number
  • 232-911-6
KEGG
UNII
Properties
[C6H10O5]n
Molar mass Variable
Appearance White powder
Insoluble
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Amylopectin /ˌæmɪlˈpɛktɪn/ is a water-insoluble[1][2] polysaccharide and highly branched polymer of α-glucose units found in plants. It is one of the two components of starch, the other being amylose.

Relation of amylopectin to starch granule

Plants store starch within specialized organelles called amyloplasts. To generate energy, the plant hydrolyzes the starch, releasing the glucose subunits. Humans and other animals that eat plant foods also use amylase, an enzyme that assists in breaking down amylopectin, to initiate the hydrolysis of starch.[3]

Starch is made of about 70–80% amylopectin by weight, though it varies depending on the source. For example, it ranges from lower percent content in long-grain rice, amylomaize, and russet potatoes to 100% in glutinous rice, waxy potato starch, and waxy corn. Amylopectin is highly branched, being formed of 2,000 to 200,000 glucose units. Its inner chains are formed of 20–24 glucose subunits.

Structure of the amylopectin molecule

Dissolved amylopectin starch has a lower tendency of retrogradation (a partial recrystallization after cooking—a part of the staling process) during storage and cooling. For this main reason, the waxy starches are used in different applications mainly as a thickening agent or stabilizer.

  1. ^ "Amylose, Amylopectin (starch)". GMO Compass. Archived from the original on 2010-12-31. Retrieved 2011-02-07.
  2. ^ Green, Mark M.; Blankenhorn, Glenn; Hart, Harold (November 1975). "Which Starch Fraction is Water-Soluble, Amylose or Amylopectin?". Journal of Chemical Education. 52 (11): 729. Bibcode:1975JChEd..52..729G. doi:10.1021/ed052p729. Pure amylopectin that has not degraded is readily soluble in cold water Subscription required for online access.
  3. ^ "28: Starch Hydrolysis". Biology LibreTexts. 2016-04-12. Retrieved 2022-04-29.

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