Calixarene

IUPAC definition

calixarenes: Originally macrocyclic compounds capable of assuming a basket (or 'calix') shaped conformation. They are formed from p-hydrocarbyl phenols and formaldehyde. The term now applies to a variety of derivatives by substitution of the hydrocarbon cyclo{oligo(1,3-phenylene)methylene}.[1]

A calixarene is a macrocycle or cyclic oligomer based on a methylene-linked phenols. With hydrophobic cavities that can hold smaller molecules or ions, calixarenes belong to the class of cavitands known in host–guest chemistry.[2]

  1. ^ "calixarenes". Gold Book. IUPAC. doi:10.1351/goldbook.C00783. Retrieved 1 April 2024.
  2. ^ Gutsche, C. David (1989). Calixarenes. Cambridge: Royal Society of Chemistry. ISBN 978-0-85186-385-6.

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