Manganese(III) fluoride

Manganese(III) fluoride
Manganese(III) fluoride
Names
IUPAC name
Manganese(III) fluoride
Other names
Manganese trifluoride, manganic fluoride
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.029.096 Edit this at Wikidata
EC Number
  • 232-006-6
RTECS number
  • OP0882600
UNII
  • InChI=1S/3FH.Mn/h3*1H;/q;;;+3/p-3 checkY
    Key: SRVINXWCFNHIQZ-UHFFFAOYSA-K checkY
  • InChI=1/3FH.Mn/h3*1H;/q;;;+3/p-3
    Key: SRVINXWCFNHIQZ-DFZHHIFOAX
  • [Mn+3].[F-].[F-].[F-]
Properties
MnF3
Molar mass 111.938 g/mol
Appearance purple-pink powder
hygroscopic
Density 3.54 g/cm3
Melting point > 600 °C (1,112 °F; 873 K) (decomposes)
hydrolysis
+10,500·10−6 cm3/mol
Structure
Monoclinic, mS48
C2/c, No. 15
distorted octahedral
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
toxic fumes
GHS labelling:[1]
GHS03: OxidizingGHS06: Toxic
Danger
H272, H301, H312, H315, H319, H332, H335
P220, P261, P280, P301+P310, P305+P351+P338
Related compounds
Other anions
manganese(III) oxide, manganese(III) acetate
Other cations
chromium(III) fluoride, iron(III) fluoride. cobalt(III) fluoride
Related compounds
manganese(II) fluoride, manganese(IV) fluoride
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Manganese(III) fluoride (also known as Manganese trifluoride) is the inorganic compound with the formula MnF3. This red/purplish solid is useful for converting hydrocarbons into fluorocarbons, i.e., it is a fluorination agent.[2] It forms a hydrate and many derivatives.

  1. ^ GHS: sigma-aldrich 339296 [dead link]
  2. ^ Burley, G. A.; Taylor, R. (2004). "Manganese(III) Fluoride". Encyclopedia of Reagents for Organic Synthesis. J. Wiley & Sons. doi:10.1002/047084289X.rn00411. ISBN 0-471-93623-5.

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