Back Nitrosoniový ion Czech Nitrosylkation German Nitrosonio Spanish نیتروسونیم Persian Ion nitrosonium French Nitrozóniumion Hungarian Nitrosonium ID Nitrosonio Italian ニトロソニウムイオン Japanese ნიტროზონიუმის იონი Georgian
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| Names | |||
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| IUPAC name
Nitrilooxonium
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| Systematic IUPAC name
Oxidonitrogen(1+)[1] | |||
| Other names
Nitrosonium
Iminooxidanium | |||
| Identifiers | |||
3D model (JSmol)
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| Abbreviations | NO(+) | ||
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| ChemSpider | |||
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PubChem CID
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CompTox Dashboard (EPA)
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Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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The nitrosonium ion is NO+, in which the nitrogen atom is bonded to an oxygen atom with a bond order of 3, and the overall diatomic species bears a positive charge. It can be viewed as nitric oxide with one electron removed. This ion is usually obtained as the following salts: NOClO4, NOSO4H (nitrosylsulfuric acid, more descriptively written ONSO3OH) and NOBF4. The ClO−4 and BF−4 salts are slightly soluble in acetonitrile CH3CN. NOBF4 can be purified by sublimation at 200–250 °C and 0.01 mmHg (1.3 Pa).[2]
- ^ Nomenclature of Inorganic Chemistry : IUPAC Recommendations 2005 (Red Book). Cambridge: The Royal Society of Chemistry. 2005. p. 315. ISBN 978-0-85404-438-2.
- ^ Olah, George A.; Surya Prakash, G. K.; Wang, Qi; Li, Xing-ya; Surya Prakash, G. K.; Hu, Jinbo (15 October 2004). "Nitrosonium Tetrafluoroborate". Encyclopedia of Reagents for Organic Synthesis: rn058.pub2. doi:10.1002/047084289X.rn058.pub2. ISBN 0471936235.