Palladium fluoride is the name of a series of binary compounds of palladium and fluorine . These include:
Palladium(II) fluoride or palladium difluoride, PdF2
Palladium(II,IV) fluoride or palladium trifluoride, PdF3 . It is not palladium(III) fluoride (which is unknown), and is often described as palladium(II) hexafluoropalladate(IV), PdII [PdIV F6 ][ 1]
Palladium(IV) fluoride , or palladium tetrafluoride, PdF4
Palladium(VI) fluoride , or palladium hexafluoride, PdF6 , which is calculated to be stable[ 2]
Palladium-fluorine coordination complexes have been developed to catalyse the synthesis of aryl fluorides , which are otherwise difficult to make .[ 3] [ 4]
^ Greenwood, Norman N. ; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann . pp. 1152–1153. ISBN 978-0-08-037941-8 .
^ Aullón, G.; Alvarez, S. (2007). "On the Existence of Molecular Palladium(VI) Compounds: Palladium Hexafluoride". Inorg. Chem. 46 (7): 2700–2703. doi :10.1021/ic0623819 . PMID 17326630 .
^ Grushin, V. V. (2002). "Palladium Fluoride Complexes: One More Step toward Metal-Mediated C-F Bond Formation". Chem. Eur. J. 8 (5): 1006–1014. doi :10.1002/1521-3765(20020301)8:5<1006::AID-CHEM1006>3.0.CO;2-M . PMID 11891886 .
^ Watson, D. A.; Su, M.; Teverovskiy, G.; Zhang, Y.; García-Fortanet, J.; Kinzel, T.; Buchwald, S. L. (2009). "Formation of ArF from LPdAr(F): Catalytic Conversion of Aryl Triflates to Aryl Fluorides" . Science . 325 (5948): 1661–1664. Bibcode :2009Sci...325.1661W . doi :10.1126/science.1178239 . PMC 3038120 . PMID 19679769 .