Phosphorus pentaiodide

Phosphorus pentaiodide
Names
IUPAC name
Phosphorus(V) iodide
Other names
  • Pentaiodophosphorane
  • Pentaiodophosphorus
  • Phosphorus pentaiodide
  • Tetraiodophosphonium iodide
Identifiers
Properties
PI5
Molar mass 665.49611 g·mol−1
Appearance Brown-black crystalline solid (disputed)[1]
Melting point 41 °C (106 °F; 314 K) (disputed)[1]
Related compounds
Related compounds
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Phosphorus pentaiodide is a hypothetical inorganic compound with formula PI5. The existence of this compound has been claimed intermittently since the early 1900s.[2] The claim is disputed: "The pentaiodide does not exist (except perhaps as PI3·I2, but certainly not as [PI4]+I...)".[3]

  1. ^ a b Cite error: The named reference claim was invoked but never defined (see the help page).
  2. ^ Walker and Johnson, J. Chem. Soc. 87, 1595 (1905).
  3. ^ Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. ISBN 978-0-08-037941-8.

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