Potassium ferrocyanide

Potassium hexacyanidoferrate(II)
Potassium ferrocyanide trihydrate
Names
IUPAC name
Potassium hexacyanidoferrate(II)
Other names
  • (Yellow) Prussiate of Potash[1]
  • Potassium hexacyanoferrate (II) trihydrate
  • Tetrapotassium ferrocyanide trihydrate
  • Ferrate hexacyano tetrapotassium trihydrate[2]
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.034.279 Edit this at Wikidata
EC Number
  • 237-722-2
E number E536 (acidity regulators, ...)
UNII
  • InChI=1S/6CN.Fe.4K.3H2O/c6*1-2;;;;;;;;/h;;;;;;;;;;;3*1H2/q6*-1;+2;4*+1;;;
    Key: UTYXJYFJPBYDKY-UHFFFAOYSA-N
  • [K+].[K+].N#C[Fe-4](C#N)(C#N)(C#N)(C#N)C#N.[K+].[K+]
Properties
K4[Fe(CN)6]
Molar mass 368.35 g/mol (anhydrous)
422.388 g/mol (trihydrate)
Appearance Light yellow, crystalline granules
Density 1.85 g/cm3 (trihydrate)
Boiling point (decomposes)
trihydrate
28.9 g/100 mL (20 °C)
Solubility insoluble in ethanol, ether
−130.0·10−6 cm3/mol
Hazards
GHS labelling:
GHS09: Environmental hazard
Warning
H411
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 1: Exposure would cause irritation but only minor residual injury. E.g. turpentineFlammability 0: Will not burn. E.g. waterInstability 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g. liquid nitrogenSpecial hazards (white): no code
1
0
0
Flash point Non-flammable
Lethal dose or concentration (LD, LC):
6400 mg/kg (oral, rat)[3]
Related compounds
Other anions
Potassium ferricyanide
Other cations
Sodium ferrocyanide
Prussian blue
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Potassium hexacyanidoferrate(II) is the inorganic compound with formula K4[Fe(CN)6]·3H2O. It is the potassium salt of the coordination complex [Fe(CN)6]4−. This salt forms lemon-yellow monoclinic crystals.

  1. ^ Five Hundred Useful and Amusing Experiments in Chemistry, and in the Arts and Manufactures: With Observations on the Properties Employed, and Their Application to Useful Purposes. Thomas Tegg. 1825.
  2. ^ Cite error: The named reference JTBaker was invoked but never defined (see the help page).
  3. ^ https://chem.nlm.nih.gov/chemidplus/rn/13943-58-3 [dead link]

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