Silver chlorite

Silver chlorite
Names
	IUPAC name Silver chlorite
	Other names Silver(I) chlorite;
Identifiers
CAS Number	7783-91-7 ;
3D model (JSmol)	Interactive image;
ChemSpider	8031311;
PubChem CID	9855611;
	InChI InChI=1S/Ag.ClHO2/c;2-1-3/h;(H,2,3)/q+1;/p-1;
	SMILES [O-]Cl=O.[Ag+];
Properties
Chemical formula	AgClO2
Molar mass	175.32 g/mol
Appearance	Slightly yellow solid
Melting point	156 °C (313 °F; 429 K) (decomposes)
Solubility in water	0.45 g/100ml
Refractive index (nD)	2.1
Structure
Crystal structure	Orthorhombic
Space group	Pcca
Lattice constant	a = 6.075 Å, b = 6.689 Å, c = 6.123 Å
Thermochemistry
Heat capacity (C)	20.81 cal/deg
Std molar; entropy (S⦵298)	32.16 cal/deg
Std enthalpy of; formation (ΔfH⦵298)	0.0 kcal/mol
Hazards
	GHS labelling:
Pictograms
Related compounds
Other anions	Silver chlorate; Silver perchlorate; Silver hypochlorite
Other cations	Sodium chlorite
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references

Silver chlorite is a chemical compound with the formula AgClO₂. This slightly yellow solid is shock sensitive and has an orthorhombic crystal structure.

^ ^a ^b A. G. Massey; N. R. Thompson; B. F. G. Johnson (2016). The Chemistry of Copper, Silver and Gold (Ebook). Pergamon International Library of Science, Technology, Engineering and Social Studies: Elsevier Science. p. 108. ISBN 9781483181691.
^ ^a ^b F. Solymosi (1968). "The Thermal Stability and Some Physical Properties of Silver Chlorite, Chlorate and Perchlorate*". Zeitschrift für Physikalische Chemie. 57 (1). Oldenbourg Wissenschaftsverlag: 1–18. doi:10.1524/zpch.1968.57.1_2.001. S2CID 102195060.
^ M. Okuda; M. Ishihara; M. Yamanaka; S. Ohba; Y. Saito (1990). "Structures of lead chlorite, magnesium chlorite hexahydrate and silver chlorite". Acta Crystallogr. 46 (10): 1755–1759. Bibcode:1990AcCrC..46.1755O. doi:10.1107/S010827019000066X.
^ ^a ^b Wendell V. Smith; Kenneth S. Pitzer; Wendell M. Latimer (1937). "Silver Chlorite: Its Heat Capacity from 15 to 300K., Free Energy and Heat of Solution and Entropy. The Entropy of Chlorite Ion". J. Am. Chem. Soc. 59 (12): 2640–2642. doi:10.1021/ja01291a046.

[soln-1] A. G. Massey; N. R. Thompson; B. F. G. Johnson (2016). The Chemistry of Copper, Silver and Gold (Ebook). Pergamon International Library of Science, Technology, Engineering and Social Studies: Elsevier Science. p. 108. ISBN 9781483181691.

[ag-2] F. Solymosi (1968). "The Thermal Stability and Some Physical Properties of Silver Chlorite, Chlorate and Perchlorate*". Zeitschrift für Physikalische Chemie. 57 (1). Oldenbourg Wissenschaftsverlag: 1–18. doi:10.1524/zpch.1968.57.1_2.001. S2CID 102195060.

[cry-3] M. Okuda; M. Ishihara; M. Yamanaka; S. Ohba; Y. Saito (1990). "Structures of lead chlorite, magnesium chlorite hexahydrate and silver chlorite". Acta Crystallogr. 46 (10): 1755–1759. Bibcode:1990AcCrC..46.1755O. doi:10.1107/S010827019000066X.

[heat-4] Wendell V. Smith; Kenneth S. Pitzer; Wendell M. Latimer (1937). "Silver Chlorite: Its Heat Capacity from 15 to 300K., Free Energy and Heat of Solution and Entropy. The Entropy of Chlorite Ion". J. Am. Chem. Soc. 59 (12): 2640–2642. doi:10.1021/ja01291a046.

[2]

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[3]

[4]

Names

IUPAC name Silver chlorite
Other names Silver(I) chlorite
Identifiers
CAS Number	7783-91-7^Y
3D model (JSmol)	Interactive image
ChemSpider	8031311
PubChem CID	9855611
InChI InChI=1S/Ag.ClHO2/c;2-1-3/h;(H,2,3)/q+1;/p-1
SMILES [O-]Cl=O.[Ag+]
Properties
Chemical formula	AgClO₂
Molar mass	175.32 g/mol
Appearance	Slightly yellow solid
Melting point	156 °C (313 °F; 429 K)^[2] (decomposes)
Solubility in water	0.45 g/100ml^[1]
Refractive index (n_D)	2.1^[2]
Structure^[3]
Crystal structure	Orthorhombic
Space group	Pcca
Lattice constant	a = 6.075 Å, b = 6.689 Å, c = 6.123 Å
Thermochemistry
Heat capacity (C)	20.81 cal/deg^[4]
Std molar entropy (S^⦵₂₉₈)	32.16 cal/deg^[4]
Std enthalpy of formation (Δ_fH^⦵₂₉₈)	0.0 kcal/mol^[1]
Hazards
GHS labelling:
Pictograms
Related compounds
Other anions	Silver chlorate Silver perchlorate Silver hypochlorite
Other cations	Sodium chlorite
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references

Silver chlorite

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