Sulfur dichloride

Sulfur dichloride
Structure and dimensions of the sulfur dichloride molecule
Ball-and-stick model of sulfur dichloride
Ball-and-stick model of sulfur dichloride
Space-filling model of sulfur dichloride
Space-filling model of sulfur dichloride
Names
IUPAC name
  • Dichlorosulfane
  • Sulfur dichloride
  • Sulfur(II) chloride
Other names
  • Chloro thiohypobromite
  • Dichloro sulfide
  • Sulphur chloride
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.031.014 Edit this at Wikidata
EC Number
  • 234-129-0
RTECS number
  • WS4500000
UNII
UN number 1828
  • InChI=1S/Cl2S/c1-3-2
    Key: FWMUJAIKEJWSSY-UHFFFAOYSA-N
  • InChI=1/Cl2S/c1-3-2
    Key: FWMUJAIKEJWSSY-UHFFFAOYAS
  • ClSCl
Properties
SCl2
Molar mass 102.96 g·mol−1
Appearance Cherry-red liquid
Odor Pungent
Density 1.621 g/cm3
Melting point −121.0 °C (−185.8 °F; 152.2 K)
Boiling point 59 °C (138 °F; 332 K) (decomposes)
Insoluble, reacts slowly
−49.4·10−6 cm3/mol
1.5570
Structure
C2v
Bent
Hazards
GHS labelling:
GHS05: CorrosiveGHS07: Exclamation markGHS09: Environmental hazard
Danger
H314, H335, H400
P260, P261, P264, P271, P273, P280, P301+P330+P331, P303+P361+P353, P304+P340, P305+P351+P338, P310, P312, P321, P363, P391, P403+P233, P405, P501
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 3: Short exposure could cause serious temporary or residual injury. E.g. chlorine gasFlammability 1: Must be pre-heated before ignition can occur. Flash point over 93 °C (200 °F). E.g. canola oilInstability 1: Normally stable, but can become unstable at elevated temperatures and pressures. E.g. calciumSpecial hazards (white): no code
3
1
1
234 °C (453 °F; 507 K)
Safety data sheet (SDS) ICSC 1661
Related compounds
Related
Related compounds
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Sulfur dichloride is the chemical compound with the formula SCl2. This cherry-red liquid is the simplest sulfur chloride and one of the most common, and it is used as a precursor to organosulfur compounds. It is a highly corrosive and toxic substance, and it reacts on contact with water to form chlorine-containing acids.


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