Tetrachloroethylene

Tetrachloroethylene
Tetrachloroethylene
Tetrachloroethylene
Tetrachloroethylene
Tetrachloroethylene
  Carbon, C
  Chlorine, Cl
Names
Preferred IUPAC name
Tetrachloroethene
Other names
Carbon bichloride; Carbon dichloride (Carboneum Dichloratum); Dicarbon tetrachloride;[1] Ethylene tetrachloride; Perchlor; Perchloroethene; Perchloroethylene; Chlorethose[2]
Identifiers
3D model (JSmol)
Abbreviations PCE; Perc; Per
1304635
ChEBI
ChEMBL
ChemSpider
ECHA InfoCard 100.004.388 Edit this at Wikidata
EC Number
  • 204-825-9
101142
KEGG
RTECS number
  • KX3850000
UNII
UN number 1897
  • InChI=1S/C2Cl4/c3-1(4)2(5)6 checkY
    Key: CYTYCFOTNPOANT-UHFFFAOYSA-N checkY
  • InChI=1/C2Cl4/c3-1(4)2(5)6
    Key: CYTYCFOTNPOANT-UHFFFAOYAO
  • ClC(Cl)=C(Cl)Cl
Properties
C2Cl4
Molar mass 165.82 g/mol
Appearance Clear, very refractive, colorless liquid
Odor Mild, sharp and sweetish[3]
Density 1.622 g/cm3
Melting point −22.0 to −22.7 °C (−7.6 to −8.9 °F; 251.2 to 250.5 K)
Boiling point 121.1 °C (250.0 °F; 394.2 K)
0.15 g/L (25 °C)
Vapor pressure 14 mmHg (20 °C)[3]
−81.6·10−6 cm3/mol
1.505
Viscosity 0.89 cP at 25 °C
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
Inhalation of vapours can cause anaesthesia and respiratory irritation. Causes irritation in contact with skin and eyes with no residual injury.
GHS labelling:
GHS08: Health hazardGHS09: Environmental hazard
Warning
H351, H411
P201, P202, P273, P281, P308+P313, P391, P405, P501
NFPA 704 (fire diamond)
Flash point Not flammable
Lethal dose or concentration (LD, LC):
3420 mg/kg (oral, rat)[4]
2629 mg/kg (oral, rat), >10000 mg/kg (dermal, rat)[5]
4000 ppm (rat, 4 hr)
5200 ppm (mouse, 4 hr)
4964 ppm (rat, 8 hr)[6]
NIOSH (US health exposure limits):
PEL (Permissible)
TWA 100 ppm
C 200 ppm (for 5 minutes in any 3-hour period), with a maximum peak of 300 ppm[3]
REL (Recommended)
Ca Minimize workplace exposure concentrations.[3]
IDLH (Immediate danger)
Ca [150 ppm][3]
Safety data sheet (SDS) External MSDS
Related compounds
Related analogous organohalides
Tetrafluoroethylene
Tetrabromoethylene
Tetraiodoethylene
Related compounds
Trichloroethylene
Dichloroethylene
1,1,2,2-Tetrachloroethane
Carbon tetrachloride
Supplementary data page
Tetrachloroethylene (data page)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
☒N verify (what is checkY☒N ?)

Tetrachloroethylene, also known as perchloroethylene[a] or under the systematic name tetrachloroethene, and abbreviations such as perc (or PERC), and PCE, is a chlorocarbon with the formula Cl2C=CCl2. It is a non-flammable, stable, colorless and heavy liquid widely used for dry cleaning of fabrics, hence it is sometimes called "dry-cleaning fluid". It also has its uses as an effective automotive brake cleaner. It has a mild sweet, sharp odor, detectable by most people at a concentration of 50 ppm.[8]

  1. ^ C. Chabrie "General Method for the Preparation of Carbon Fluorides" in Journal - Chemical Society, London. (1890). UK: Chemical Society.
  2. ^ Justus Liebigs Annalen der Chemie. (1845). Germany: Verlag Chemie. Page 277
  3. ^ a b c d e NIOSH Pocket Guide to Chemical Hazards. "#0599". National Institute for Occupational Safety and Health (NIOSH).
  4. ^ Sigma Aldrich Tetrachloroethylene MSDS
  5. ^ Fischer Scientific Tetrachloroethylene MSDS
  6. ^ "Tetrachloroethylene". Immediately Dangerous to Life or Health Concentrations (IDLH). National Institute for Occupational Safety and Health (NIOSH).
  7. ^ "Compound Summary: Tetrachloroethylene". PubChem. Retrieved 9 September 2020.
  8. ^ Ethel Browning, Toxicity of Industrial Organic Solvents (1953, [ https://archive.org/details/cftri.3112toxicityofindust0000ethe/page/182/mode/1up pages 182-185]


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