Tollens' reagent

Tollens' test for aldehyde: left side positive (silver mirror), right side negative
Ball-and-stick model of the diamminesilver(I) complex

Tollens' reagent (chemical formula ) is a chemical reagent used to distinguish between aldehydes and ketones along with some alpha-hydroxy ketones which can tautomerize into aldehydes. The reagent consists of a solution of silver nitrate, ammonium hydroxide and some sodium hydroxide (to maintain a basic pH of the reagent solution). It was named after its discoverer, the German chemist Bernhard Tollens.[1] A positive test with Tollens' reagent is indicated by the precipitation of elemental silver, often producing a characteristic "silver mirror" on the inner surface of the reaction vessel.

  1. ^ Tollens, B. (1882). "Ueber ammon-alkalische Silberlösung als Reagens auf Aldehyd" [On an ammonical alkaline silver solution as a reagent for aldehydes] (PDF). Berichte der Deutschen Chemischen Gesellschaft (in German). 15 (2): 1635–1639. doi:10.1002/cber.18820150243.

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